Reference: A. S. Filatov and M. A. Petrukhina "Gas Phase Synthesis and X-ray Crystal Structures of Supramolecular Networks with Bromocorannulene: Similarities and Differences with their Corannulene Analogs" J. Organomet. Chem., 2008, 693, 1590-1596. (Invited article for the F. A. Cotton memorial issue.) (Elsevier copyright.)
Small perturbations in the structure of the ligand lead to the changes in the final crystal packing of the material, even though electronically both ligands are very similar.
Synopsis figure

Small perturbations in the structure of the ligand lead to the changes in the final crystal packing of the material, even though electronically both ligands are very similar.
Synopsis figure

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